[N-(Carboxylatomethyl)aspartato(3-)](ethylenediamine)cobalt(III) trihydrate

• Autoři: MADEROVÁ J.; MAREK Jaromír; PAVELČÍK F.
• Rok publikování: 2003
• Druh: Článek v odborném periodiku
• Časopis / Zdroj: Acta Crystallographica Section C: Crystal Structure
• Fakulta / Pracoviště MU: Přírodovědecká fakulta
• Obor: Anorganická chemie
• Klíčová slova: structure; cobalt(III)
• Popis: The mononuclear title complex, [Co(C6H6NO6)(C2H8N2)].3H2O, contains an octahedrally coordinated Co(III) atom. The N-(carboxymethyl)aspartate moiety is coordinated as a tetradentate ligand, providing an OONO-donor set and forming two trans five-membered chelate rings and one six-membered chelate ring. A seven-membered chelate ring is also formed, which consists of part of the six-membered chelate ring and part of one of the five-membered chelate rings. The crystal structure of the complex is stabilized by hydrogen bonds with three water molecules.

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